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AutomatedDynamic Headspace DHS

AutomatedDynamic Headspace DHS

AutomatedDynamic Headspace DHS

Product catalog summary
Overview of Dynamic Headspace (DHS) Technology
The Dynamic Headspace (DHS) option for the GERSTEL MPS autosampler automates the extraction and concentration of volatile organic compounds (VOCs) from liquid or solid samples. This technique combines the sensitivity of Purge and Trap with the ease and productivity of Headspace analysis, offering enhanced detection limits and eliminating carryover.

Key Features and Benefits
  • Automation and Flexibility: The DHS system provides complete automation from sample extraction to introduction, with user-defined parameters for extraction time, flow, and temperature. It supports a wide range of adsorbents and allows for the use of new traps for each sample to prevent cross-contamination.
  • Enhanced Detection Limits: The system offers lower detection limits compared to static headspace and SPME techniques, with efficient trapping on selectable adsorbent tubes.
  • High Productivity: The GERSTEL MAESTRO software integrates control of the entire process, optimizing productivity through features like PrepAhead functionality and high throughput capabilities.
  • Reliable and Reproducible Results: The system's inert, valve-free sample path minimizes analyte discrimination and cross-contamination, ensuring reliable results.

System Components and Operation
  • Adsorbents: Tenax TA is commonly used, but other adsorbents can be selected based on application needs. Multi-bed adsorbent tubes can be used for a wide range of analyte properties.
  • Sample Handling: Samples are stored in standard headspace vials and can be thermostated between 4 °C to 200 °C. Agitation and controlled gas purging enhance extraction efficiency.
  • Thermal Desorption Unit (TDU): Analytes are thermally desorbed from the trap and introduced into a GC/MS system for analysis.

Comparison with Other Techniques
In comparative studies, DHS demonstrated higher analyte response and lower relative standard deviations than static headspace and SPME, particularly in the analysis of coffee powder.

GERSTEL MAESTRO Software
The MAESTRO software provides unified control of GERSTEL modules, enabling simple method generation and integration with chromatography data systems. It supports real-time monitoring and flexible operation, enhancing laboratory productivity.

DHSlarge Module
The DHSlarge module extends the DHS capabilities to analyze large or inhomogeneous samples, such as consumer products and packaging, in containers up to 1L. This module supports unattended analysis and parallel processing for increased efficiency.
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Catalog excerpts

AutomatedDynamic Headspace DHS-1

Enhanced Detection Limits Carryover Eliminated Highest Productivity and Throughput Most Flexible Automated Solution Available

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AutomatedDynamic Headspace DHS-2

Automated Dynamic Headspace DHS The Dynamic Headspace technique combines the sensitivity and low detection limits of Purge and Trap with the ease of handling, high productivity and ruggedness of Headspace analysis. The Dynamic Headspace (DHS) option for the GERSTEL MPS autosampler, an industry standard, offers complete automation of the dynamic headspace technique. The DHS station is used to extract and concentrate VOCs from liquid or solid samples placed in standard headspace vials. The headspace above the sample is purged and analytes are concentrated on a user selectable adsorbent-filled trap....

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AutomatedDynamic Headspace DHS-3

DHS Benefits 1 Low detection limits • Exhaustive purge of sample headspace • Efficient trapping on selectable adsorbent tube • Direct and quantitative, split or splitless transfer from trap to GC/MS system • Lower detection limits than static headspace, SPME, and other widely used techniques 2 Reliable and reproducible • Inert, unique valve free sample path: No analyte discrimination, no cross contamination • A new trap can be selected for every sample to eliminate any risk of cross-contamination • Headspace purge technique, limits the risk of system contamination from sample foaming • Automated...

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AutomatedDynamic Headspace DHS-4

GERSTEL DHSlarge GERSTEL DHSlarge Autosampler The DHS can be extended with the DHSlarge module to perform analysis of large or inhomogeneous bulk samples. For example, consumer products, packaging or flooring material can be placed directly in sample containers up to 1L in volume. Sample holders are available for flooring material, eliminating interfering emissions from the edges of the cut sample. Purge periods can be introduced to simulate air exchange conditions in environmental chambers. A series of analyses can be performed on a sample to determine emission behavior over time. DHS operation...

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